Browsing Research Output by Author "Huijsmans, Carlijn A.A."
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Improved metathesis lifetime: chelating pyridinyl-alcoholato ligands in the second generation Grubbs precatalyst
Du Toit, Jean I.; Huijsmans, Carlijn A.A.; Jordaan, Johannes H.L.; Van Sittert, Cornelia G.C.E.; Vosloo, Hermanus C.M.; Jordaan, Margaritha (MDPI, 2014)Hemilabile ligands can release a free coordination site “on demand” of an incoming nucleophilic substrate while occupying it otherwise. This is believed to increase the thermal stability and activity of catalytic systems ...