Browsing Faculty of Natural and Agricultural Sciences by Subject "Lifetime"
Now showing items 1-2 of 2
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Improved metathesis lifetime: chelating pyridinyl-alcoholato ligands in the second generation Grubbs precatalyst
(MDPI, 2014)Hemilabile ligands can release a free coordination site “on demand” of an incoming nucleophilic substrate while occupying it otherwise. This is believed to increase the thermal stability and activity of catalytic systems ... -
Industrial viability of homogeneous olefin metathesis: beneficiation of linear alpha olefins with the diphenyl-substituted pyridinyl alcoholato ruthenium carbene precatalyst
(Elsevier, 2016)The catalytic performance of the diphenyl-substituted pyridinyl alcoholato ruthenium carbene precatalyst of the Grubbs 2-type was optimized for 1-octene metathesis by varying operating parameters, such as reaction temperature ...