Abstract:
Gas to liquids (GTL) technology, although an attractive method for meeting
liquid fuel requirements into the future, has an inherent concern regarding the
environmental impact of dealing with the large amount of carbon dioxide that
is generated. In this investigation, the potential to reduce this carbon dioxide
footprint by utilising process heat from high temperature helium at 950oC
downstream of a High Temperature Gas (cooled) Reactor (HTGR) is
examined.
The study compares a base case steam methane reformer (SMR) heated by
the combustion of natural gas to a nuclear heated steam methane reformer
heated by hot helium from one HTGR. It has been shown that it is possible to
reduce the carbon dioxide footprint almost entirely for the synthesis block of a
GTL facility. Process heat integration from one HTGR has the potential to
reduce the carbon dioxide footprint of an SMR by approximately 42 tons per
hour.
The full potential of one HTGR in terms of carbon dioxide reduction for a GTL
facility was also investigated. This was achieved by estimating the cogeneration
potential impact on carbon dioxide emissions where the residual
heat in the helium stream downstream of the reformer was used for power
generation. The overall amount of carbon dioxide reduction from both the
reformer and power generation facility was then quantified and an economic
study was completed. The study shows that with one HTGR it would be
possible to reduce the carbon dioxide emissions of a GTL facility by almost
200 t/h if nuclear process heat was used in the reformer and nuclear power
generation was used instead of conventional coal based power generation.
Results from the economic study show that industry would have to incur an
operating cost increase of approximately R200, at current natural gas prices,
to reduce their carbon dioxide emissions by one ton if nuclear energy was
used as a process heat source and for power generation.
Description:
Thesis (M.Sc. Engineering Sciences (Nuclear Engineering))--North-West University, Potchefstroom Campus, 2010.