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dc.contributor.authorVan der Gryp, Percyen_US
dc.contributor.authorBarnard, Anroen_US
dc.contributor.authorCronje, Jean-Pierreen_US
dc.contributor.authorDe Vlieger, Dennisen_US
dc.contributor.authorMarx, Sanetteen_US
dc.contributor.authorVosloo, Hermanus C.M.en_US
dc.date.accessioned2012-02-29T09:49:12Z
dc.date.available2012-02-29T09:49:12Z
dc.date.issued2010en_US
dc.identifier.citationVan der Gryp, P. et al. 2010. Separation of different metathesis grubbs-type catalysts using organic solvent nanofiltration. Journal of membrane science, 353(1-2):70-77, May. [http://www.sciencedirect.com/science/article/pii/S0376738810001407]en_US
dc.identifier.issn0376-7388en_US
dc.identifier.urihttp://hdl.handle.net/10394/5890
dc.identifier.urihttps://doi.org/10.1016/j.memsci.2010.02.032
dc.description.abstractIn this paper, the challenge of separating and re-using homogeneous catalysts from their post-reaction mixture in the field of metathesis is addressed using organic solvent nanofiltration (OSN). A coupled reaction–separation process was applied for the metathesis reaction of 1-octene to 7-tetradecene and ethene. Five different Grubbs-type catalysts and the STARMEM™ series of OSN membranes were used. It was found that the STARMEM™ 228 membrane successfully separates the different catalysts from their post-reaction mixtures to below 9 ppm. The coupled reaction–separation and recycling process also increased the turnover number from 1400 for a single pass reaction to 5500 for the overall consecutive reaction–separation steps of four cycles. The OSN process was further characterized for mixtures of 1-octene, 1-tetradecene and 7-tetradecene by varying operating pressures and solvent concentration
dc.publisherElsevieren_US
dc.titleSeparation of different metathesis grubbs-type catalysts using organic solvent nanofiltrationen_US
dc.contributor.researchID11328819 - Van der Gryp, Percy
dc.contributor.researchID13038877 - Barnard, Anro
dc.contributor.researchID10216847 - Marx, Sanette
dc.contributor.researchID10063552 - Vosloo, Hermanus Cornelius Moolman


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