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dc.contributor.authorLe Roux, C.J.
dc.contributor.authorKriek, R.J.
dc.contributor.authorGans, P.
dc.date.accessioned2016-02-25T09:47:44Z
dc.date.available2016-02-25T09:47:44Z
dc.date.issued2014
dc.identifier.citationLe Roux, C.J. et al. 2014. Complexation of palladium(II) with thiocyanate: a spectrophotometric investigation. Journal of coordination chemistry, 67(9):1520-1529. [https://doi.org/10.1080/00958972.2014.918264]en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389 (Online)
dc.identifier.urihttp://hdl.handle.net/10394/16425
dc.identifier.urihttps://www.tandfonline.com/doi/abs/10.1080/00958972.2014.918264
dc.identifier.urihttps://doi.org/10.1080/00958972.2014.918264
dc.description.abstractComplex-formation of Pd(II) with thiocyanate has been investigated by spectrophotometry at 25 °C and an ionic strength of 1.0 M. The formation constants, βn, for the palladium(II) thiocyanate complexes [Pd(SCN)n(H2O)4–n]2–n (n = 0–4), have been determined and the values are: log β1 = 8.14, log β2 = 15.46, log β3 = 21.94, and log β4 = 27.42. These complexes are generally accepted to be square planar. However, a five-coordinate species, i.e. [Pd(SCN5]3–, with a formation constant of log β5 = 31.94 seems to exist and is proposed to be square pyramidal. Molar absorption spectra for all the complexes in question have been obtaineden_US
dc.description.sponsorshipAnglo American Platinum Limiteden_US
dc.language.isoenen_US
dc.publisherTaylor & Francisen_US
dc.subjectPalladium(II)en_US
dc.subjectThiocyanateen_US
dc.subjectComplexationen_US
dc.subjectFormation constantsen_US
dc.subjectspectrophotometryen_US
dc.titleComplexation of palladium(II) with thiocyanate: a spectrophotometric investigationen_US
dc.typeArticleen_US
dc.contributor.researchID12138886 - Le Roux, Cornelius Johannes
dc.contributor.researchID13238477 - Kriek, Roelof Jacobus


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