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Browsing Faculty of Natural and Agricultural Sciences by Subject "Second generation grubbs precatalyst"
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Improved metathesis lifetime: chelating pyridinyl-alcoholato ligands in the second generation Grubbs precatalyst (MDPI, 2014)Hemilabile ligands can release a free coordination site “on demand” of an incoming nucleophilic substrate while occupying it otherwise. This is believed to increase the thermal stability and activity of catalytic systems ...