dc.contributor.author | Musyoka, Nicholas | |
dc.contributor.author | Bessarabov, Dmitri | |
dc.contributor.author | Ren, Jianwei | |
dc.contributor.author | Annamalai, Perushini | |
dc.contributor.author | Langmi, Henrietta W. | |
dc.date.accessioned | 2017-04-07T12:49:38Z | |
dc.date.available | 2017-04-07T12:49:38Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Musyoka, N.M. et al. 2016. Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications. Research on chemical intermediates, 42(6):5299-5307. [http://link.springer.com/journal/11164] | en_US |
dc.identifier.issn | 0922-6168 | |
dc.identifier.issn | 1568-5675 (Online) | |
dc.identifier.uri | http://hdl.handle.net/10394/21235 | |
dc.identifier.uri | http://dx.doi.org/10.1007/s11164-015-2361-2 | |
dc.identifier.uri | http://link.springer.com/article/10.1007/s11164-015-2361-2 | |
dc.description.abstract | Metal–organic frameworks (MOFs) hybrid composites have recently attracted considerable attention in hydrogen storage applications. In this study a hybrid composite of zeolite templated carbon (ZTC) and Cr-based MOF (MIL-101) was synthesised by adding the templated carbon in situ during the synthesis of MIL-101(Cr). The obtained sample was fully characterized and hydrogen adsorption measurements performed at 77 K up to 1 bar. The results showed that the surface areas and the hydrogen uptake capacities of individual MIL-101 (2552 m2 g−1, 1.91 wt%) and zeolite templated carbon (2577 m2 g−1, 2.39 wt%) could be enhanced when a hybrid MIL-101(Cr)/ZTC composite (2957 m2 g−1, 2.55 wt%) was synthesized. The procedure presents a simple way for enhancement of hydrogen uptake capacity of the individual Cr-MOF and templated carbon samples | en_US |
dc.language.iso | en | en_US |
dc.publisher | Springer | en_US |
dc.subject | Metal organic framework (MOF) | en_US |
dc.subject | Zeolite templated carbon (ZTC) | en_US |
dc.subject | Hybrid MIL-101(Cr)/ZTC | en_US |
dc.subject | Hydrogen uptake | en_US |
dc.subject | Surface area | en_US |
dc.title | Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications | en_US |
dc.type | Article | en_US |
dc.contributor.researchID | 22730389 - Bessarabov, Dmitri Georgievich | |