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dc.contributor.authorStratz, S. Adam
dc.contributor.authorJones, Steven J.
dc.contributor.authorMathuthu, Manny
dc.date.accessioned2018-07-27T08:09:05Z
dc.date.available2018-07-27T08:09:05Z
dc.date.issued2017
dc.identifier.citationStratz, S.A. et al. 2017. Gas chemical adsorption characterization of lanthanide hexafluoroacetylacetonates. Journal of Radioanalytical and Nuclear Chemistry, 312:355-360. [https://link.springer.com/article/10.1007/s10967-017-5232-z]
dc.identifier.issn0236-5731
dc.identifier.issn1588-2780 (Online)
dc.identifier.urihttps://link.springer.com/article/10.1007/s10967-017-5232-z
dc.identifier.urihttp://hdl.handle.net/10394/30362
dc.description.abstractNewly-established adsorption enthalpy and entropy values of 12 lanthanide hexafluoroacetylacetonates, denoted Ln[hfac]4, along with the experimental and theoretical methodology used to obtain these values, are presented for the first time. The results of this work can be used in conjunction with theoretical modeling techniques to optimize a large-scale gas-phase separation experiment using isothermal chromatography. The results to date indicate average adsorption enthalpy and entropy values of the 12 Ln[hfac]4 complexes ranging from −33 to −139 kJ/mol K and −299 to −557 J/mol, respectively.
dc.language.isoen
dc.publisherSpringer
dc.publisherSpringer
dc.subjectNuclear forensics
dc.subjectHexafluoroacetylacetone
dc.subjectRare earth separations
dc.subjectNuclear security
dc.subjectPost-detonation
dc.titleGas chemical adsorption characterization of lanthanide hexafluoroacetylacetonates
dc.typeArticle
dc.contributor.researchID24429872 - Mathuthu, Manny


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